Publication:
Site-selective catalytic carboxylation of unsaturated hydrocarbons with CO2 and water

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Date
2017-08-16
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Authors
Gaydou, Morgane ; Moragas, Toni ; Juliá Hernández, Francisco ; Martin, Ruben
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Publisher
American Chemical Society
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DOI
https://doi.org/10.1021/jacs.7b07637
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Description
© 2017 American Chemical Society. This manuscript version is made available under the CC-BY-NC 4.0 license http://creativecommons.org/licenses/by-nc/4.0/. This document is the Published version of a Published Work that appeared in final form in Journal of the American Chemical Society. To access the final edited and published work see https://doi.org/10.1021/jacs.7b07637
Abstract
A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO2 to a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is described. This platform unlocks an opportunity to catalytically repurpose three abundant, orthogonal feedstocks under mild conditions.
Citation
J. Am. Chem. Soc. 2017, 139,12161–12164
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