Publication:
Maximizing the [c2]daisy chain to lasso ratio through competitive self-templating clipping reactions

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CC_Accepted version MS-Competitive STC RXNs_QOS2022.pdf(1.41 MB)
Date
2021-11-30
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Authors
Saura-Sanmartin, Adrian ; Pastor Vivero, Aurelia ; Martinez-Cuezva, Alberto ; Berná Cánovas, José
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Publisher
Royal Society of Chemistry
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Química Orgánica
DOI
https://doi.org/10.1039/D1CC05942D
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info:eu-repo/semantics/article
Description
©2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted, version of a Published Work that appeared in final form in [Chemical Communications]. To access the final edited and published work see[https://doi.org/10.1039/D1CC05942D]
Abstract
Self-templating two-component coupling reactions allowed the isolation of two threaded products with different molecular sizes: a lasso-type [1]rotaxane and a [c2]daisy chain rotaxane. Their distribution in the final reaction mixture varies as a factor of the concentration of the reactants. Through this methodology we obtained a large 84-membered cyclic multistation [2]rotaxane.
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Mechanical bond , [c2]DAISY CHAIN ROTAXANE , Lasso compounds , Clipping reactions , NMR Diffusion experiments , Supramolecular chemistry
Citation
Chem. Commun., 2022, 58, 290-293.
URI
http://hdl.handle.net/10201/130296
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