Publication: Effective encapsulation of C60 by metal-organic frameworks with polyamide macrocyclic linkers
Loading...
Date
2021
Authors
Saura-Sanmartin, Adrian ; Martinez-Cuezva, Alberto ; Marín-Luna, Marta ; Bautista Cerezo, Delia ; Berná Cánovas, José
item.page.secondaryauthor
item.page.director
Publisher
WILEY-VCH VERLAG GMBH
publication.page.editor
publication.page.department
Description
©2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
This document is the Accepted, version of a Published Work that appeared in final form in [Angew. Chem. Int]. To access the final edited and published work see[https://doi.org/10.1002/anie.202100996]
Abstract
A flexible benzylic amide macrocycle, functionalized with two carboxylic acid groups, was employed as the organic ligand for the preparation of robust copper(II)- and zinc(II)-based metal-organic frameworks. These polymers crystallized in the C2/m space group of the monoclinic crystal system, creating non-interpenetrated channels in one direction with an extraordinary solvent-accessible volume of 46%. Unlike metal-organic rotaxane frameworks having benzylic amide macrocycles as linkers, the absence of the thread in these novel reticular materials causes a decrease of dimensionality and an improvement of pore size and dynamic guest adaptability. We studied the incorporation of fullerene C60 inside the adjustable pocket generated between two macrocycles connected to the same dinuclear clusters, occupying a remarkable 98% of the cavities inside the network. The use of these materials as hosts for the selective recognition of different fullerenes was evaluated, mainly encapsulating the smaller size fullerene derivative in several mixtures of C60 and C70.
publication.page.subject
Citation
item.page.embargo
Collections
Ir a Estadísticas
Este ítem está sujeto a una licencia Creative Commons. Licencia Creative Commons