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Internal Coulombic assistance in intermolecular frustrated Lewis pair activation of dihydrogen

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dc.contributor.authorRey Planells, Alicia
dc.contributor.authorEspinosa Ferao, Arturo
dc.contributor.authorStreubel, Rainer
dc.contributor.authorFrontera, Antonio
dc.contributor.departmentQuímica Orgánica
dc.date.accessioned2025-03-12T07:02:45Z
dc.date.available2025-03-12T07:02:45Z
dc.date.issued2024-02-15
dc.description© 2024 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. This manuscript version is made available under the CC-BY-NC 4.0 license http://creativecommons.org/licenses/by-nc/4.0/ This document is the Published Manuscript version of a Published Work that appeared in final form in New Journal of Chemistry. To access the final edited and published work see https://doi.org/10.1039/D4NJ00523Fes
dc.description.abstract1,3-Zwitterions consisting of a phosphonium cation linked to a silicate centre through a one-atom bridge, X3P–E–SiY4 (3), are computationally studied. Their phosphonium acidic group together with a Lewis base constitute a frustrated Lewis pair (FLP) in the activation of H2, with the silicate side-arm providing Coulombic stabilization to the positive charge at the Lewis base.es
dc.formatapplication/pdfes
dc.format.extent5es
dc.identifier.doihttps://doi.org/10.1039/D4NJ00523F
dc.identifier.eisbnNew Journal of Chemistry, 2024, Vol. 48, Issue 11, pp. 4675–4679es
dc.identifier.issnPrint: 1144-0546
dc.identifier.issnElectronic: 1369-9261
dc.identifier.urihttp://hdl.handle.net/10201/151572
dc.languageenges
dc.publisherRoyal Society of Chemistryes
dc.relationA. F. thanks MICIU/AEI of Spain (PID2020-115637GB-I00, FEDER funds) for financial support and the Alexander von Humboldt foundation for the J. C. Mutis award.es
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2024/nj/d4nj00523fes
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAtribución-NoComercial 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.titleInternal Coulombic assistance in intermolecular frustrated Lewis pair activation of dihydrogenes
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
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