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Mechanical bonding of rigid MORFs using a tetratopic rotaxane

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dc.contributor.authorSaura Sanmartín, Adrián
dc.contributor.authorCutillas Font, Guillermo
dc.contributor.authorMartinez-Cuezva, Alberto
dc.contributor.authorAlajarín, Mateo
dc.contributor.authorEsteban Betegón, Fátima
dc.contributor.authorPena Sánchez, Pilar
dc.contributor.authorGándara, Felipe
dc.contributor.authorBerná Cánovas, José
dc.contributor.departmentQuímica Orgánica
dc.contributor.departmentNuevas Arquitecturas en Quı´mica de Materiales, Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC)
dc.date.accessioned2024-07-02T08:10:33Z
dc.date.available2024-07-02T08:10:33Z
dc.date.created2024
dc.date.issued2024-05-28
dc.description© The Royal Society of Chemistry 2024. This manuscript version is made available under the CC-BY-NC 4.0 license http://creativecommons.org/licenses/by-nc/4.0/ This document is the Published version of a Published Work that appeared in final form in Chemical Communications. To access the final edited and published work see https://doi.org/10.1039/D4CC02065Kes
dc.description.abstractThe preparation of highly rigid cobalt(II)- and copper(II)–organic frameworks incorporating a tetralactam [2]rotaxane as a ligand is described. The interlocked ligand is functionalized with two pairs of carboxylate groups placed at each counterpart, thus limiting its dynamics within the crystal. The solid structure of the metal–organic rotaxane frameworks showed different, unprecedented polycatenation modes of grids, depending on the employed metal, providing great rigidity to the structures. This rigidity has been evaluated by using single crystal X-ray diffraction analyses of the cobalt(II)–organic frameworks embedded in different solvents, observing that the lattices remain unchanged. Thus, this research demonstrates that rigid and robust materials with permanent porosity can be achieved using dynamic ligands.es
dc.formatapplication/pdfes
dc.format.extent4es
dc.identifier.doihttps://doi.org/10.1039/D4CC02065K
dc.identifier.eisbnChemical Communications, 2024, Vol. 60, pp. 6431-6434es
dc.identifier.issnPrint: 1359-7345
dc.identifier.issnElectronic: 1364-548X
dc.identifier.urihttp://hdl.handle.net/10201/142793
dc.languageenges
dc.publisherRoyal Society of Chemistry
dc.relationThis work was supported by the MICIN/AEI/10.13039/501100011033 (Project PID2020-113686GB-I00, PID2021-123287OB-I00), Fundacion Seneca-CARM (Project 21907/PI/22 and contract 21442/FPI/20) and Ministerio de Universidades of the Government of Spain through European Union – NextGenerationEU (Margarita Salas postdoctoral contract)es
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc02065k
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAtribución-NoComercial 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.subjectRotaxanees
dc.subjectMetal-organic frameworkses
dc.subjectCrystalline materialses
dc.subjectRigid materialses
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Química::547 - Química orgánicaes
dc.titleMechanical bonding of rigid MORFs using a tetratopic rotaxanees
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
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