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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Martínez Cuezva, Alberto | - |
dc.contributor.author | Pastor Vivero, Aurelia | - |
dc.contributor.author | Cioncoloni, Giacomo | - |
dc.contributor.author | Orenes Martínez, Raúl Angel | - |
dc.contributor.author | Alajarín, Mateo | - |
dc.contributor.author | Symes, Mark D. | - |
dc.contributor.author | Berná Cánovas, José | - |
dc.contributor.other | Departamento de Química Orgánica, Facultad de Química, Regional Campus of International Excellence “Campus Mare Nostrum”, Universidad de Murcia, Murcia, Spain | es |
dc.contributor.other | WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow G12 8QQ, UK | es |
dc.date.accessioned | 2015-10-26T13:47:55Z | - |
dc.date.available | 2015-10-26T13:47:55Z | - |
dc.date.created | 2015 | - |
dc.date.issued | 2015-03-18 | - |
dc.identifier.uri | http://hdl.handle.net/10201/46719 | - |
dc.description | http://dx.doi.org/10.1039/C5SC00790A | es |
dc.description.abstract | A cyclic network of chemical reactions has been conceived for exchanging the dynamic behaviour of di(acylamino)pyridine-based rotaxanes and surrogates. X-ray diffraction studies revealed the intercomponent interactions in these interlocked compounds and were consistent with those found in solution by dynamic NMR experiments. This particular binding site was incorporated into a molecular shuttle enabled for accessing two states with an outstanding positional discrimination through chemical manipulation. Furthermore, the ability of the di(acylamino)pyridine domain to associate with external binders with a complementary array of HB donor and acceptor sites was exploited for the advance of an unprecedented electrochemical switch operating through a reversible anion radical recognition process. | es |
dc.description.sponsorship | This work was supported by the MICINN (Projects CTQ2008-05827/BQU and CTQ2009-12216/BQU), and Fundacion Seneca-CARM (Project 08661/PI/08). A.M.-C. thanks the Marie Curie COFUND and U-IMPACT programs for a postdoctoral contract (Grant Agreement 267143). M.D.S. thanks the University of Glasgow for a Kelvin-Smith Research Fellowship and the EPSRC for a Small Equipment grant. | es |
dc.format | application/pdf | es |
dc.format.extent | 8 | es |
dc.language | eng | es |
dc.relation.ispartof | CHEMICAL SCIENCE, VOL. 6 (5), 3087-3094 (2015) | es |
dc.rights | info:eu-repo/semantics/openAccess | es |
dc.subject | Rotaxane | es |
dc.subject | Hydrogen bond | es |
dc.subject | Synthesis | es |
dc.subject | Molecular recognition | es |
dc.title | Versatile control of the submolecular motion of di(acylamino)pyridine-based [2]rotaxanes | es |
dc.type | info:eu-repo/semantics/article | es |
Aparece en las colecciones: | Artículos: Química Orgánica |
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Fichero | Descripción | Tamaño | Formato | |
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2015CS_PV_DAP-RTXs.pdf | 898,43 kB | Adobe PDF | Visualizar/Abrir |
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