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https://doi.org/10.1021/acs.inorgchem.9b02813
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| Título: | Triazole-Containing [FeFe] Hydrogenase Mimics: Synthesis and Electrocatalytic Behavior |
| Fecha de publicación: | 2-dic-2019 |
| Editorial: | American Chemical Society |
| Cita bibliográfica: | Inorganic Chemistry 58 (23), 2019:16267−16278 |
| ISSN: | Print: 0020-1669 Electronic: 1520-510X |
| Materias relacionadas: | CDU::5 - Ciencias puras y naturales::54 - Química::547 - Química orgánica |
| Palabras clave: | Triazole Hydrogenase Mimics Electrocatalytic |
| Resumen: | Through a Cu-catalyzed Huisgen cycloaddition between terminal alkynes and azides (CuAAC) reaction, azide [(μ-SCH2)2N(4- N3C6H4)Fe2(CO)6] has demonstrated to be a robust and versatile reagent able to incorporate the [(μ-SR)2Fe2(CO)6] fragment on a wide range of substrates, ranging from aromatic compounds to nucleosides, metallocenes, or redox and luminescent markers. The [FeIFeI]/[Fe0FeI] and [Fe0FeI]/[Fe0Fe0] reduction potentials of the triazole derivatives prepared are comparable to those of other aminodithiolate (adt) Fe−Fe hydrogenase mimics. The presence of the triazole linker influences the electrochemical behavior of these complexes depending on the strength of the acid employed. |
| Autor/es principal/es: | Merinero, Alba D. Collado, Alba Casarrubios, Luis Gómez Gallego, Mar Ramírez de Arellano, Carmen Caballero, Antonio Zapata Fernández, Fabiola Sierra, Miguel A. |
| Facultad/Departamentos/Servicios: | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU:: Química Orgánica |
| URI: | http://hdl.handle.net/10201/138825 |
| DOI: | https://doi.org/10.1021/acs.inorgchem.9b02813 |
| Tipo de documento: | info:eu-repo/semantics/article |
| Número páginas / Extensión: | 12 |
| Derechos: | info:eu-repo/semantics/openAccess Attribution-NoCommercial-NoDerivatives 4.0 Internacional |
| Descripción: | ©2019. This manuscript version is made available under the CC-BY 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted, version of a Published Work that appeared in final form in Inorganic Chemistry. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.9b02813 |
| Aparece en las colecciones: | Artículos: Química Orgánica |
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| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| 54 Inorg Chem 2019 58 16267.pdf | 2,55 MB | Adobe PDF |  Visualizar/Abrir |
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