1. Digitum: Repositorio Institucional de la Universidad de Murcia
  2. Investigación
  3. Departamentos de la UM
  4. Química Orgánica
  5. Artículos: Química Orgánica
Por favor, use este identificador para citar o enlazar este ítem: https://doi.org/10.1039/D2QO00481J

Registro completo de metadatos
Campo DCValorLengua/Idioma
dc.contributor.authorPérez Martínez, Jesús de María-
dc.contributor.authorAlajarín, Mateo-
dc.contributor.authorMartinez-Cuezva, Alberto-
dc.contributor.authorBerná Cánovas, José-
dc.contributor.otherFacultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Orgánicaes
dc.date.accessioned2023-04-24T11:11:06Z-
dc.date.available2023-04-24T11:11:06Z-
dc.date.created2022-
dc.date.issued2022-04-06-
dc.identifier.citationOrg. Chem. Front., 2022,9, 2690-2696es
dc.identifier.issn2052-4129-
dc.identifier.urihttp://hdl.handle.net/10201/130269-
dc.description©2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted, version of a Published Work that appeared in final form in [Organic Chemistry Frontiers]. To access the final edited and published work see[https://doi.org/10.1039/D2QO00481J]es
dc.description.abstractThe modulation of the catalytic activity of degenerate succinamide-based [2]rotaxanes by changes at their macrocyclic component is disclosed herein. These systems, bearing an acyclic secondary amine function at the thread as the active site and incorporating different polyamide macrocycles, were evaluated as organocatalysts in iminium- and enamine-type processes. The results of kinetic studies clearly show a drastic variation of their catalytic efficiency, which apparently correlated with the electronics and dynamics of the entwined macrocycle.es
dc.formatapplication/pdfes
dc.format.extent6es
dc.languageenges
dc.publisherRoyal Society of Chemistryes
dc.relationThis work was supported by the Spanish Ministry of Science and Innovation (project PID2020-113686GB-I00/MICINN/AEI/10.13039/501100011033) and the Fundacion Seneca-CARM (project 20811/PI/18).es
dc.relation.isreplacedbyhttps://pubs.rsc.org/en/content/articlelanding/2022/QO/D2QO00481Jes
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectMechanical bondes
dc.subjectRotaxanees
dc.subjectOrganocatalysises
dc.subjectKinetic studieses
dc.subjectDegenerate [2] rotaxanees
dc.subjectDynamicses
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Química::547 - Química orgánicaes
dc.titleModulating the catalytic activity by the mechanical bond: organocatalysis with polyamide [2]rotaxanes bearing a secondary amino function at the threades
dc.typeinfo:eu-repo/semantics/articlees
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2022/QO/D2QO00481Jes
dc.identifier.doihttps://doi.org/10.1039/D2QO00481J-
Aparece en las colecciones:Artículos: Química Orgánica

Ficheros en este ítem:
Fichero Descripción TamañoFormato 
OCF_Accepted MS_Modulation catalysis_QOS2022_UMU.pdfModulating the Catalytic Activity by the Mechanical Bond: Organocatalysis with Polyamide [2]Rotaxanes bearing a Secondary Amino Function at the Thread_QOS-UMU965,43 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro sencillo del ítem Mostrar el registro PREMIS del ítem  Estadísticas


Este ítem está sujeto a una licencia Creative Commons Licencia Creative Commons Creative Commons