Browsing by Subject "Carboxylation"

Now showing 1 - 1 of 1
  • Thumbnail Image
    Publication
    Open Access
    Site-selective, remote sp3 C−H carboxylation enabled by the merger of photoredox and nickel catalysis
    (Wiley, 2019-06-06) Sahoo, Basudev; Bellotti, Peter; Juliá Hernández, Francisco; Meng, Qing-Yuan; Crespi, Stefano; König, Burkhard; Martin, Ruben; Química Inorgánica
    A photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C@H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain.