Please use this identifier to cite or link to this item: 10.1002/chem.201703574

Title: The Coordination and Supramolecular Chemistry of Gold Metalloligands
Issue Date: 13-Oct-2017
Date of creation: 2017
Publisher: Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Citation: Chem. Eur. J. 24(1), 32-46 (2018)
ISSN: 1521-3765
Related subjects: CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica
Keywords: Gold
Self-Assembly
Coordination Complexes
Abstract: This review article deals with the use of gold metalloligands as building blocks for the assembly of heterometallic complexes. Several families of gold complexes decorated with crown-ether, amide, pyridine, bipyridine, terpyridine, carboxylato, aminoacid or π-alkyne binding sites have been reported. Adducts of these metalloligands with alkaline or transition metal cations, or with transition metal or lanthanide complexes, have been isolated and structurally characterized. The reported heterometallic species range from simple dinuclear complexes to self-assembled supramolecules, coordination polymers or solids. New structural motifs have been found in these complexes. Most of these metalloligands and complexes are photoluminescent and some of them show switchable emissions based on the formation and rupture of metallophilic contacts. Potential applications as sensors, sensitizers, in vivo imaging agents and anticancer drugs are envisaged.
Primary author: Gil-Rubio, Juan
Vicente, José
Faculty / Departments / Services: Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánica
Editor's version: https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201703574
URI: http://hdl.handle.net/10201/88162
DOI: 10.1002/chem.201703574
Document type: info:eu-repo/semantics/article
Number of pages / Extensions: 17
Rights: info:eu-repo/semantics/openAccess
Sponsor: Ministerio de Economía y Competitividad (grant CTQ2015-69568-P, with FEDER support). Fundación Séneca (grant 19890/GERM/15)
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