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Title: Synthesis of the First Example of a Cyclometallated ortho-Nitrophenyl Complex. X-Ray Molecular Structure of Carbonyl(chloro)bis(o-nitrophenyl-C,O)rhodium
Issue Date: 26-Nov-2019
Date of creation: 1985
Related subjects: CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica
Keywords: organometallated Rh nitrophenyl Hg transmetalation carbonyl RX ciclometallated ortometallated
Abstract: The complex [RhCI(C0)2]2 reacts at room temperature with [Hg(2-C6H4N02)2] (1 : 2) to give metallic mercury and the complex [Rh(2-C6H4N(0)o)2CI(CO)w] hose crystal structure shows an octahedral co-ordination with one oxygen atom of each nitrophenyl ligand co-ordinated to the rhodium atom.
Primary author: Vicente, J.
Martín, J.
Chicote, M. T.
Solans, X.
Miravitlles, C.
Faculty / Departments / Services: Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánica
Document type: info:eu-repo/semantics/article
Number of pages / Extensions: 2
Rights: info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 International
Appears in Collections:Artículos

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