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| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.contributor.author | Vicente, J. | - |
| dc.contributor.author | Abad, J. A. | - |
| dc.contributor.author | Gil-Rubio, J. | - |
| dc.contributor.author | Jones, P. G. | - |
| dc.contributor.other | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánica | es |
| dc.date.accessioned | 2019-11-26T09:40:13Z | - |
| dc.date.available | 2019-11-26T09:40:13Z | - |
| dc.date.created | 1994 | - |
| dc.date.issued | 2019-11-26 | - |
| dc.identifier.uri | http://hdl.handle.net/10201/76965 | - |
| dc.description.abstract | Stoichiometric reactions of arylpalladium compounds with alkynes give spirocyclic organic and organometallic compounds. The compound bis{r?-C-O-(2,3,4-trimethoxy-6-acetylphenyl)} di(p-chloro)dipalladium(II) reacts with diphenylacetylene or ethyl 3-phenylpropiolate giving 6-ace@-1,2,3,4- tetraphenyl-9,10-dimethoxy-spiro[4.5]1,3,6,9-decatetraen-8- one and 6-acetyl-1,3-dicarboxyethyl-2,4-diphenyl-9,lO-dimethoxy- spiro[4,5]1,3,6,9-decatetraen-8-one, respectively. A rrallylpalladium complex, 7~~-{6-acetyl-1,2,3,4_tetraphenyl- 8,9,lO-trimetho~-spiro[4,5]1,3,9-decatrien-6-enyl}(2,2’-bipyridine) palladium(II) trifluoromethylsulfonate solvated, with one molecule of 1,2-dichloroethane, has also been isolated and its structure determined by X-ray diffraction studies. | es |
| dc.format | application/pdf | es |
| dc.format.extent | 4 | es |
| dc.language | eng | es |
| dc.rights | info:eu-repo/semantics/openAccess | es |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject | aryl allyl Pd(2) Hg transmetalation organometallic organic RX spiro acetylene insertion acetyl aryl cyclometallated ortometallated | es |
| dc.subject.other | CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica | es |
| dc.title | Palladium-assisted formation of carbon-carbon bonds Part 2.” Stoichiometric synthesis of spirocyclic compounds. X-ray structure of a wallylic palladium intermediate | es |
| dc.type | info:eu-repo/semantics/article | es |
| Aparece en las colecciones: | Artículos: Química Inorgánica | |
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| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| Palladium.pdf | 334,7 kB | Adobe PDF |  Visualizar/Abrir |
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