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dc.contributor.authorVicente, J.-
dc.contributor.authorAbad, J. A.-
dc.contributor.authorCara, G.-
dc.contributor.authorGutierrez-Jugo, J. F.-
dc.contributor.otherFacultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánicaes
dc.date.accessioned2019-11-25T12:06:37Z-
dc.date.available2019-11-25T12:06:37Z-
dc.date.created1992-
dc.date.issued2019-11-25-
dc.identifier.urihttp://hdl.handle.net/10201/76924-
dc.description.abstractAddition of trifluoroacetic or trifluoromethanesulfonic acid to solutions of thaIlium(l1l) trifluoroacetate in acetone results in formation of the compounds [TI{CH,C(O)Me},X] (X = CF,CO, l a or CF,SO, 1 b. Compound 1 b reacts in a 1 : 1 ratio with LiCl or KBr giving the halogeno derivatives [TI{CH,C(O)Me},Y] (Y = CI 2a or Br 2b). Compound 2a reacts with [N(PPh,),]CI yielding the anionic complex “(PPh,),] [TI{CH,C(O)Me},CI,] 3. The reaction of 1 b with 2,2‘-bipyridine (bipy) gives [{TI[CH,- C(O)Me],(p-CF,SO,) (bipy)},] 4 in which each thallium atom has a distorted six-co-ordination with the acetonyl ligands in trans positions and two cis positions occupied by two bridging triflate anions.es
dc.formatapplication/pdfes
dc.format.extent3es
dc.languageenges
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectorganometallic Tl metallation ketonyl RX-
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica-
dc.titleNon-arylic DiorganothalIium Derivatives obtained by Metallation. Synthesis and Isolation of the First DiketonyIthalIium (III) Complexes-
dc.typeinfo:eu-repo/semantics/articlees
Aparece en las colecciones:Artículos: Química Inorgánica

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