Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10201/76924
Twittear
Registro completo de metadatos
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Vicente, J. | - |
dc.contributor.author | Abad, J. A. | - |
dc.contributor.author | Cara, G. | - |
dc.contributor.author | Gutierrez-Jugo, J. F. | - |
dc.contributor.other | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánica | es |
dc.date.accessioned | 2019-11-25T12:06:37Z | - |
dc.date.available | 2019-11-25T12:06:37Z | - |
dc.date.created | 1992 | - |
dc.date.issued | 2019-11-25 | - |
dc.identifier.uri | http://hdl.handle.net/10201/76924 | - |
dc.description.abstract | Addition of trifluoroacetic or trifluoromethanesulfonic acid to solutions of thaIlium(l1l) trifluoroacetate in acetone results in formation of the compounds [TI{CH,C(O)Me},X] (X = CF,CO, l a or CF,SO, 1 b. Compound 1 b reacts in a 1 : 1 ratio with LiCl or KBr giving the halogeno derivatives [TI{CH,C(O)Me},Y] (Y = CI 2a or Br 2b). Compound 2a reacts with [N(PPh,),]CI yielding the anionic complex “(PPh,),] [TI{CH,C(O)Me},CI,] 3. The reaction of 1 b with 2,2‘-bipyridine (bipy) gives [{TI[CH,- C(O)Me],(p-CF,SO,) (bipy)},] 4 in which each thallium atom has a distorted six-co-ordination with the acetonyl ligands in trans positions and two cis positions occupied by two bridging triflate anions. | es |
dc.format | application/pdf | es |
dc.format.extent | 3 | es |
dc.language | eng | es |
dc.rights | info:eu-repo/semantics/openAccess | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | organometallic Tl metallation ketonyl RX | - |
dc.subject.other | CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica | - |
dc.title | Non-arylic DiorganothalIium Derivatives obtained by Metallation. Synthesis and Isolation of the First DiketonyIthalIium (III) Complexes | - |
dc.type | info:eu-repo/semantics/article | es |
Aparece en las colecciones: | Artículos: Química Inorgánica |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Diorganot ha1 I ium Derivatives obtained.pdf | 416,56 kB | Adobe PDF | Visualizar/Abrir |
Este ítem está sujeto a una licencia Creative Commons Licencia Creative Commons