Please use this identifier to cite or link to this item: http://hdl.handle.net/10201/76922

Title: Preparation and Properties of Stable Salts Containing Mono- or Bis-(pentafluorophenyl)aurate(I) and Mono-, Tris-, or Tetrakis (pentafluorophenyl)aurate(III) Ions
Issue Date: 25-Nov-2019
Date of creation: 1976
Related subjects: CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica
Keywords: organometallics Au(3) Au(1) oxidation C6F5 anionic
Abstract: Tetrahydrothiophen (tht) and/or chloride may readily be displaced from [CIAu(tht)] or [Cl,Au(tht)] with LiC,F, to give novel organometallic anionic com-plexes of gold(^) or gold(II1).
Sztmwzary Tetrahydrothiophen (tht) and/or chloride may The reaction of [CIAu(tht)] with an excess (4: 1) of readily be displaced from [CIAu(tht)] or [Cl,Au(tht)] LiC,F, gives rise to the displacement of both ligands and to with LiC,F, to give novel organometallic anionic com- the formation of bis(pentafluorophenyl)aurate(I), which is plexes of gold(^) or gold(II1). isolated (60% yield) as complex (4) [Bun4N] [(C,F,),Au].
Primary author: Usón, R.
Laguna, A.
Vicente, J.
Faculty / Departments / Services: Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánica
URI: http://hdl.handle.net/10201/76922
Document type: info:eu-repo/semantics/article
Number of pages / Extensions: 2
Rights: info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 International
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