Please use this identifier to cite or link to this item: http://hdl.handle.net/10201/3614

Title: Dihaloperhaloaryl triphenylarsine gold(III) complexes
Issue Date: 1975
Related subjects: CDU::5 - Ciencias puras y naturales
Keywords: Aril Aryl organometalico organometallics Au(III) Au(I) gold
Oro
Arsina
Arsine
AsPh3
C6F5
C6Cl5
Oxidation
Oxidación
Abstract: When C6CISAuAsPh3 reacts with halogens, oxidation of the gold(I) complex and formation of X2Au(C6C15)AsPh3 (X = Cl, Br, I) take place. However, when C6F5AuAsPh3 reacts with halogens, oxidation is only observed in the case of Cl2 whilst I2 (totally) and Br2 (partially) split the Au-C bond. This behaviour is contrary to that observed with C6F5AuPPh3 and halogens, where the tendency to split the Au-C bond decreases in the sequence C! > Br > I.
Primary author: Usón, Rafael
Laguna, Antonio
Vicente, José
Faculty / Departments / Services: Quimica Inorgánica Zaragoza
Quimica Inorgánica Murcia
Published in: J. Organomet. Chem. 86 (1975) 415
URI: http://hdl.handle.net/10201/3614
Document type: info:eu-repo/semantics/article
Number of pages / Extensions: 8
Rights: info:eu-repo/semantics/openAccess
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