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dc.contributor.authorDavies, Jacob-
dc.contributor.authorLyonnet, Julien R.-
dc.contributor.authorCarvalho, Bjorn-
dc.contributor.authorSahoo, Basudev-
dc.contributor.authorDay, Craig S.-
dc.contributor.authorJuliá Hernández, Francisco-
dc.contributor.authorDuan, Yaya-
dc.contributor.authorObst, Marc-
dc.contributor.authorNorrby, Per-Ola-
dc.contributor.authorVelasco-Rubio, Álvaro-
dc.contributor.authorHopmann, Kathrin H-
dc.contributor.authorMartin, Ruben-
dc.contributor.authorObst, Marc-
dc.contributor.authorPer-OLa, Norrby-
dc.date.accessioned2025-01-07T11:32:51Z-
dc.date.available2025-01-07T11:32:51Z-
dc.date.issued2024-01-09-
dc.identifier.citationJ. Am. Chem. Soc. 2024, 146, 3, 1753–1759es
dc.identifier.issnPrint: 0002-7863-
dc.identifier.issnElectronic: 1520-5126-
dc.identifier.urihttp://hdl.handle.net/10201/147929-
dc.description© 2024 The Authors. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Published version of a Published Work that appeared in final form in Journal of the American Chemical Society. To access the final edited and published work see https://doi.org/10.1021/jacs.3c11205-
dc.description.abstractHerein, we report the direct carboxylation of unactivated secondary alkyl bromides enabled by the merger of photoredox and nickel catalysis, a previously inaccessible endeavor in the carboxylation arena. Site-selectivity is dictated by a kinetically controlled insertion of CO2 at the initial C(sp3 )−Br site by the rapid formation of Ni(I)−alkyl species, thus avoiding undesired β-hydride elimination and chain-walking processes. Preliminary mechanistic experiments reveal the subtleties of stereoelectronic effects for guiding the reactivity and site-selectivity.-
dc.formatapplication/pdfes
dc.format.extent7es
dc.languageenges
dc.publisherAmerican Chemical Society-
dc.relationICIQ, FEDER/MCI PID2021-123801NB-I00, and European Research Council (ERC) under European Union’s Horizon 2020 research and innovation program (grant agreement 883756) for financial support.-
dc.relation.ispartofÁmbito del proyecto (Europeo, nacional o regional): Europeo Agencia/entidad financiadora: European Research Council Convocatoria: Advance Grant 2020. Nombre del proyecto: NOVOFLAT (Escaping from Flatland by “de novo” Catalytic Decarboxylation Techniques) Código: ERC-AdG-883756. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: Agencia Estatal de Investigación. Convocatoria: Proyectos Generación del Conocimiento 2021 Nombre del proyecto: Formación enlaces SP3 Carbono-carbono y carbono-heteroatomo mediante funcionalización catálica de grupos nativos. Código: PID2021-123801NB-I00-
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAlkylses
dc.subjectAnionses
dc.subjectHalogenses
dc.subjectOrganic reactionses
dc.subjectSelectivityes
dc.subject.otherCDU::5 - Ciencias puras y naturaleses
dc.titleKinetically-controlled ni-catalyzed direct carboxylation of unactivated secondary alkyl bromides without chain walkinges
dc.typeinfo:eu-repo/semantics/articlees
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/jacs.3c11205-
dc.identifier.doihttps://doi.org/10.1021/jacs.3c11205-
dc.contributor.departmentDepartamento de Química Inorgánica-
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