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| Título: | Site-selective, remote sp3 C−H carboxylation enabled by the merger of photoredox and nickel catalysis |
| Fecha de publicación: | 6-jun-2019 |
| Editorial: | Wiley |
| Cita bibliográfica: | Chem. Eur. J. 2019, 25, 9001-9005 |
| ISSN: | Print: 0947-6539
0947-6539 Electronic: 1521-3765 |
| Materias relacionadas: | CDU::5 - Ciencias puras y naturales::54 - Química |
| Palabras clave: | Carbon dioxide Carboxylation Chain-walking Nickel Photocatalysis |
| Resumen: | A photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C@H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain. |
| Autor/es principal/es: | Sahoo, Basudev Bellotti, Peter Juliá Hernández, Francisco Meng, Qing-Yuan Crespi, Stefano König, Burkhard Martin, Ruben |
| Versión del editor: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.20190 |
| URI: | http://hdl.handle.net/10201/147919 |
| DOI: | https://doi.org/10.1002/chem.201902095 |
| Tipo de documento: | info:eu-repo/semantics/article |
| Número páginas / Extensión: | 5 |
| Derechos: | info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
| Descripción: | © 2019 The Authors. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Published version of a Published Work that appeared in final form in Chemistry - A European Journal. To access the final edited and published work see https://doi.org/ 10.1002/chem.201902095 |
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| CEJ-2019-OA.pdf | This is the peer reviewed version of the following article: Chem. Eur. J. 2019, 25, 9001-9005, which has been published in final form at https://doi.org/10.1002/chem.201902095. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | 1,39 MB | Adobe PDF |  Visualizar/Abrir |
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