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| Título: | Visible-light-promoted atom transfer radical cyclization of unactivated alkyl Iodides |
| Fecha de publicación: | 6-dic-2016 |
| Cita bibliográfica: | ACS Catal 2017, 7 (1), 409-412 |
| ISSN: | Electronic: 2155-5435 |
| Materias relacionadas: | CDU::5 - Ciencias puras y naturales::54 - Química |
| Palabras clave: | Visible light Alkyl halide Photocatalysis Atom economy Radical cyclization |
| Resumen: | A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the perception that a canonical photoredox catalytic cycle is being operative. |
| Autor/es principal/es: | Shen, Yangyang Cornella, Josep Juliá Hernández, Francisco Martin, Ruben |
| Forma parte de: | Ámbito del proyecto (Europeo, nacional o regional): Europeo Agencia/entidad financiadora: European Research Council Convocatoria: Starting Grant 2011. Nombre del proyecto: Chasing a Fundamental Challenge in Catalysis: A Combined Cleavage of Carbon-Carbon Bonds and Carbon Dioxide for Preparing Functionalized Molecules Código: ERC-StG-277883. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO Convocatoria: Proyectos I+D+i 2015 Nombre del proyecto: CARBOXILACION DE MATERIA ORGANICA CON DIOXIDO DE CARBONO CATALIZADA POR METALES DE TRANSICION Código: CTQ2015-65496-R. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO Convocatoria: Severo Ochoa Excellence Accreditation. Nombre del proyecto: Código: SEV-2013-0319 |
| Versión del editor: | https://pubs.acs.org/doi/10.1021/acscatal.6b03205 |
| URI: | http://hdl.handle.net/10201/147918 |
| DOI: | https://doi.org/10.1021/acscatal.6b03205 |
| Tipo de documento: | info:eu-repo/semantics/article |
| Número páginas / Extensión: | 6 |
| Derechos: | info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
| Descripción: | © 2016 American Chemical Society. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Accepted version of a Published Work that appeared in final form in ACS Catalysis. To access the final edited and published work see https://doi.org/10.1021/acscatal.6b03205 |
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| ACSCatal2016-PostPrint-FJH.pdf | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acscatal.6b03205 | 2,04 MB | Adobe PDF |  Visualizar/Abrir |
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