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dc.contributor.authorGleim, Florian-
dc.contributor.authorSchnakenburg, Gregor-
dc.contributor.authorEspinosa Ferao, Arturo Francisco-
dc.contributor.authorStreubel, Rainer-
dc.date.accessioned2024-05-28T22:11:03Z-
dc.date.available2024-05-28T22:11:03Z-
dc.date.issued2024-02-07-
dc.identifier.citationChemical communications 2024, 60, 2625–2628es_ES
dc.identifier.issnPrint: 1359-7345-
dc.identifier.issnElectronic: 1364-548X-
dc.identifier.urihttp://hdl.handle.net/10201/141927-
dc.description©The Royal Society of Chemistry 2024. This manuscript version is made available under the CC-BY-NC 4.0 license http://creativecommons.org/licenses/by-nc/4.0/. This document is the Published version of a Published Work that appeared in final form in Chemical Communications. To access the final edited and published work see https://doi.org/10.1039/c5cc07600e-
dc.description.abstractHerein, we describe the synthesis of a 1,2r3 k3 -oxaphosphetane from ethylene oxide and its reactions with alkyl halides to form b-halo phosphane oxides in an Arbuzov-type reaction. When methyl triflate was used as a hard electrophile, cationic oligomerisation of 1,2-oxaphosphetanes was observed. DFT calculations indicate 1, 2-oxaphosphetan-2-iums as intermediates and reveal differences between the Arbuzov and the potential Perkow reaction pathway.-
dc.formatapplication/pdfes_ES
dc.format.extent4-
dc.languageenges_ES
dc.publisherRoyal Society of Chemistry-
dc.relationSin financiación externa a la Universidad-
dc.rightsinfo:eu-repo/semantics/openAccess*
dc.rightsAtribución-NoComercial 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.titleArbuzov meets 1,2-oxaphosphetanes: transient 1,2-oxaphosphetan-2-iums as entry point to beta-halo phosphane oxides and P-containing oligomerses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.identifier.doihttps://doi.org/10.1039/c5cc07600e-
dc.contributor.departmentDepartamento de Química Orgánica-
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