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https://doi.org/10.1039/d3dt03869f
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Biskup, David | - |
dc.contributor.author | Schnakenburg, Gregor | - |
dc.contributor.author | Espinosa Ferao, Arturo Francisco | - |
dc.contributor.author | Streubel, Rainer | - |
dc.contributor.other | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Orgánica | - |
dc.date.accessioned | 2024-05-28T22:11:02Z | - |
dc.date.available | 2024-05-28T22:11:02Z | - |
dc.date.issued | 2024-01-04 | - |
dc.identifier.citation | Dalton Transactions 2024, 53, 2517–2525 | es_ES |
dc.identifier.issn | Print: 1477-9226 | - |
dc.identifier.issn | Electronic: 1477-9234 | - |
dc.identifier.uri | http://hdl.handle.net/10201/141926 | - |
dc.description | ©2024. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted, version of a Published Work that appeared in final form in Dalton Transactions. To access the final edited and published work see https://doi.org/10.1039/d3dt03869f | - |
dc.description.abstract | While the chemistry of phosphenium compounds, including metal complexes thereof, is very well established, few derivatives having a P–H bond have been described, yet. This work describes rational access to donor-stabilised phosphenium metal complexes possessing a P–H bond using protonation reactions of stable phosphinidene complex adducts. While most Brønsted–Lowry acids yield formal 1,1-addition products at the phosphorus centre under the loss of the donor, super-strong acids having weakly coordinating anions enable access to donor-stabilised P–H hosphenium complex salts. The latter possess N-methylimidazole as a donor (to phosphorus) and the N–P interaction has been studied theoretically. | - |
dc.format | application/pdf | es_ES |
dc.format.extent | 9 | - |
dc.language | eng | es_ES |
dc.publisher | Royal Society of Chemistry | - |
dc.relation | Financial support from the Deutsche Forschungsgemeinschaft (STR 411/45-1) and the University of Bonn | - |
dc.rights | info:eu-repo/semantics/openAccess | * |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | DFT calculations | es_ES |
dc.subject | Phosphenium complexes | es_ES |
dc.title | Access to ligand-stabilized PH-containing phosphenium complexes | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.identifier.doi | https://doi.org/10.1039/d3dt03869f | - |
Aparece en las colecciones: | Artículos: Química Orgánica |
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170.-Dalto..s.pdf | 1,36 MB | Adobe PDF | ![]() Visualizar/Abrir |
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