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10.1021/ic2006869
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Título: | Synthesis, Isolation and Characterization of a Triiodo Organometallic Palladium(IV) Complex. Quantitative and Regioselective Synthesis of Two C–I Reductive Elimination Products |
Fecha de publicación: | 25-may-2011 |
Editorial: | American Chemical Society |
Cita bibliográfica: | Inorg. Chem. 2011, 50 (12), 5339-5341 |
ISSN: | 0020-1669 |
Materias relacionadas: | CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica |
Palabras clave: | Ligands / Organic Reactions / Palladium |
Resumen: | Iodine and the pincer complex [Pd(O,N,C-L)I], where L is the monoanionic ligand resulting from deprotonation of the acetyl group of the dimethylmonoketal of 2,6-diacetylpyridine, are in equilibrium at low temperatures with the Pd(IV) complex [Pd(O,N,C-L)I3], which can be isolated at –40 ºC and characterized by 1H NMR spectroscopy and Xray diffraction studies, in spite of its great instability. When the same reaction is carried out at room temperature, a quantitative reductive elimination process occurs giving L–I, which in the presence of water affords L'–I, resulting from hydrolysis of L–I. |
Autor/es principal/es: | Vicente, José Arcas, Aurelia Juliá Hernández, Francisco Bautista, Delia |
Facultad/Departamentos/Servicios: | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánica |
URI: | http://hdl.handle.net/10201/138814 |
DOI: | 10.1021/ic2006869 |
Tipo de documento: | info:eu-repo/semantics/article |
Número páginas / Extensión: | 5 |
Derechos: | info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
Descripción: | ©2011. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted version of a Published Work that appeared in final form in Inorganic Chemistry. To access the final edited and published work see https://doi.org/10.1021/ic2006869 |
Aparece en las colecciones: | Artículos: Química Inorgánica |
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