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Por favor, use este identificador para citar o enlazar este ítem: https://doi.org/10.1021/om200464s

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dc.contributor.advisorVicente, José-
dc.contributor.authorVicente, José-
dc.contributor.authorSaura-Llamas, Isabel-
dc.contributor.authorOliva-Madrid, María-José-
dc.contributor.authorGarcía-López, José-Antonio-
dc.contributor.authorBautista, Delia-
dc.contributor.otherFacultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Inorgánicaes
dc.date.accessioned2024-01-17T11:17:00Z-
dc.date.available2024-01-17T11:17:00Z-
dc.date.created2011-
dc.date.issued2011-07-28-
dc.identifier.citationOrganometallics, 2011, 30, 4624-4631es
dc.identifier.issnPrint: 0276-7333-
dc.identifier.issnElectronic: 1520-6041-
dc.identifier.urihttp://hdl.handle.net/10201/137379-
dc.descriptionThis document is made available under the CC-BY 4.0 license http://creativecommons.org/licenses/by /4.0/ This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics copyright © American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/om200464ses
dc.description.abstractA new method for high yield cyclopalladation of primary and secondary amines involving the corresponding ammonium triflates, instead of the amines generally employed is reported. The method is applied for the synthesis of Buchwald-type precatalysts [Pd(C,N-C6H4CH2CH(R’)NHR- 2)X(phosphine)] that can be easily prepared by reaction of Pd(OAc)2, one equiv of the ammonium triflate [PhCH2CH(R’)NH2R]OTf and an excess of NaX, and then treating the resulting complexes [Pd2(C,N-C6H4CH2CH(R’)NHR-2)2(μ-X)2] with the appropriate phosphine. This new method has several advantages over Buchwald´s reported synthesis.es
dc.formatapplication/pdfes
dc.format.extent26es
dc.languageenges
dc.publisherACSes
dc.relationMinisterio de Educación y Ciencia, FEDER Convocatoria: 2007 (CTQ2007-60808/BQU, C-Consolider) Fundación Séneca (04539/GERM/06)es
dc.relation.ispartofCompuestos organometálicos y de coordinación funcionalizados. Síntesis y reactividad funcionalizados (CTQ2007-60808/BQU, C-Consolider)es
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectpaladioes
dc.subjectpaladacicloses
dc.subjectcatalizadoreses
dc.subject.otherCDU::5 - Ciencias puras y naturaleses
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Químicaes
dc.titleA New Method for High Yield Cyclopalladation of Primary and Secondary Amines. Atom-Efficient Open-to-Air Inexpensive Synthesis of Buchwald-Type Precatalystses
dc.typeinfo:eu-repo/semantics/articlees
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/om200464ses
dc.identifier.doihttps://doi.org/10.1021/om200464s-
Aparece en las colecciones:Artículos: Química Inorgánica

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