Por favor, use este identificador para citar o enlazar este ítem:
https://doi.org/10.1039/D2CS00167E
Twittear
Título: | Mechanically interlocked molecules in metal–organic frameworks |
Fecha de publicación: | 25-may-2022 |
Fecha de defensa / creación: | 2022 |
Editorial: | Royal Society of Chemistry |
Cita bibliográfica: | Chemical Society Reviews., 2022,51, 4949-4976. |
ISSN: | Print: 0306-0012 Electronic: 1460-4744 |
Materias relacionadas: | CDU::5 - Ciencias puras y naturales::54 - Química::547 - Química orgánica |
Palabras clave: | Mechanical bond Reticular chemistry Metal organic frameworks Dynamics Crystal structures |
Resumen: | Mechanically interlocked molecules (MIMs) have great potential in the development of molecular machinery due to their intercomponent dynamics. The incorporation of these molecules in a condensed phase makes it possible to take advantage of the control of the motion of the components at the macroscopic level. Metal–organic frameworks (MOFs) are postulated as ideal supports for intertwined molecules. This review covers the chemistry of the mechanical bond incorporated into metal–organic frameworks from the seminal studies to the latest published advances. We first describe some fundamental concepts of MIMs and MOFs. Next, we summarize the advances in the incorporation of rotaxanes and catenanes inside MOF matrices. Finally, we conclude by showing the study of the rotaxane dynamics in MOFs and the operation of some stimuli-responsive MIMs within MOFs. In addition to emphasising some selected examples, we offer a critical opinion on the state of the art of this research field, remarking the key points on which the future of these systems should be focused. |
Autor/es principal/es: | Saura-Sanmartin, Adrian Pastor Vivero, Aurelia Martinez-Cuezva, Alberto Cutillas-Font, Guillermo Alajarín, Mateo Berná Cánovas, José |
Facultad/Departamentos/Servicios: | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Orgánica |
Versión del editor: | https://pubs.rsc.org/en/content/articlelanding/2022/CS/D2CS00167E |
URI: | http://hdl.handle.net/10201/137053 |
DOI: | https://doi.org/10.1039/D2CS00167E |
Tipo de documento: | info:eu-repo/semantics/article |
Número páginas / Extensión: | 28 |
Derechos: | info:eu-repo/semantics/openAccess Atribución 4.0 Internacional |
Descripción: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Chemical Society Reviews, copyright © Royal Society of Chemistry after peer review and technical editing by the publisher. To access the final edited and published work see: https://pubs.rsc.org/en/content/articlelanding/2022/CS/D2CS00167E |
Aparece en las colecciones: | Artículos: Química Orgánica |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
CSR_Accepted MS_MIMs in MOFs_Rvsd_QOS2022.pdf | Mechanically Interlocked Molecules in Metal-Organic Frameworks-QOS-UMU | 20,71 MB | Adobe PDF | Visualizar/Abrir |
Este ítem está sujeto a una licencia Creative Commons Licencia Creative Commons