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Título: | Effects on Rotational Dynamics of Azo and Hydrazodicarboxamide-Based Rotaxanes |
Fecha de publicación: | 28-jun-2017 |
Fecha de defensa / creación: | 2017 |
Editorial: | Multidisciplinary Digital Publishing Institute |
Cita bibliográfica: | Molecules 22, 7, 2017, 1078 |
ISSN: | 1420-3049 |
Materias relacionadas: | CDU::5 - Ciencias puras y naturales::54 - Química |
Palabras clave: | Template synthesis Hydrogen bonded rotaxanes Pirouetting motion NMR studies |
Resumen: | The synthesis of novel hydrogen-bonded [2]rotaxanes having two pyridine rings in the macrocycle and azo- and hydrazodicarboxamide-based templates decorated with four cyclohexyl groups is described. The different affinity of the binding sites for the benzylic amide macrocycle and the formation of programmed non-covalent interactions between the interlocked components have an important effect on the dynamic behavior of these compounds. Having this in mind, the chemical interconversion between the azo and hydrazo forms of the [2]rotaxane was investigated to provide a chemically-driven interlocked system enable to switch its circumrotation rate as a function of the oxidation level of the binding site. Different structural modifications were carried out to further functionalize the nitrogen of the pyridine rings, including oxidation, alkylation or protonation reactions, affording interlocked azo-derivatives whose rotation dynamics were also analyzed. |
Autor/es principal/es: | Saura Sanmartín, Adrián Martinez-Espin, Juan S. Martinez-Cuezva, Alberto Alajarín, Mateo Berna, José |
Director/es: | Berna, José |
Facultad/Departamentos/Servicios: | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Orgánica |
URI: | http://hdl.handle.net/10201/135764 |
DOI: | https://doi.org/10.3390/molecules22071078 |
Tipo de documento: | info:eu-repo/semantics/article |
Número páginas / Extensión: | 12 |
Derechos: | info:eu-repo/semantics/openAccess Atribución 4.0 Internacional |
Descripción: | © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This manuscript version is made available under the CC-BY 4.0 license https://creativecommons.org/licenses/by/4.0/ This document is the Published Manuscript version of a Published Work that appeared in final form in Molecules. To access the final edited and published work see https://doi.org/10.3390/molecules22071078 |
Aparece en las colecciones: | Artículos: Química Orgánica |
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Effects on Rotational Dynamics of Azo and Hydrazodicarboxamide-Based Rotaxanes.pdf | 2,04 MB | Adobe PDF | Visualizar/Abrir |
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