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| Título: | Maximizing the [c2]daisy chain to lasso ratio through competitive self-templating clipping reactions |
| Fecha de publicación: | 30-nov-2021 |
| Fecha de defensa / creación: | 2021 |
| Editorial: | Royal Society of Chemistry |
| Cita bibliográfica: | Chem. Commun., 2022, 58, 290-293. |
| ISSN: | 1359-7345 1364-548X |
| Materias relacionadas: | CDU::5 - Ciencias puras y naturales::54 - Química::547 - Química orgánica |
| Palabras clave: | Mechanical bond [c2]DAISY CHAIN ROTAXANE Lasso compounds Clipping reactions NMR Diffusion experiments Supramolecular chemistry |
| Resumen: | Self-templating two-component coupling reactions allowed the isolation of two threaded products with different molecular sizes: a lasso-type [1]rotaxane and a [c2]daisy chain rotaxane. Their distribution in the final reaction mixture varies as a factor of the concentration of the reactants. Through this methodology we obtained a large 84-membered cyclic multistation [2]rotaxane. |
| Autor/es principal/es: | Saura-Sanmartin, Adrian Pastor Vivero, Aurelia Martinez-Cuezva, Alberto Berná Cánovas, José |
| Facultad/Departamentos/Servicios: | Facultades, Departamentos, Servicios y Escuelas::Departamentos de la UMU::Química Orgánica |
| Versión del editor: | https://pubs.rsc.org/en/content/articlelanding/2022/CC/D1CC05942D |
| URI: | http://hdl.handle.net/10201/130296 |
| DOI: | https://doi.org/10.1039/D1CC05942D |
| Tipo de documento: | info:eu-repo/semantics/article |
| Número páginas / Extensión: | 4 |
| Derechos: | info:eu-repo/semantics/openAccess |
| Descripción: | ©2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted, version of a Published Work that appeared in final form in [Chemical Communications]. To access the final edited and published work see[https://doi.org/10.1039/D1CC05942D] |
| Aparece en las colecciones: | Artículos: Química Orgánica |
Ficheros en este ítem:
| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| CC_Accepted version MS-Competitive STC RXNs_QOS2022.pdf | Maximizing the [c2]daisy chain to lasso ratio through competitive self-templating clipping reactions-QOS_UMU | 1,45 MB | Adobe PDF |  Visualizar/Abrir |
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