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10.1039/C6GC01969B
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Lozano Rodríguez, Pedro | - |
dc.contributor.author | Gómez, Celia | - |
dc.contributor.author | Nieto Cerón, Susana | - |
dc.contributor.author | Sánchez-Gómez, Gregorio | - |
dc.contributor.author | García-Verdugo, Eduardo | - |
dc.contributor.author | Luis, Santiago V. | - |
dc.contributor.other | Facultad de Química, Departamento de Bioquímica y Biología Molecular B e Inmunología | es |
dc.date.accessioned | 2021-11-03T17:15:43Z | - |
dc.date.available | 2021-11-03T17:15:43Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Green Chemistry 2017, 19(2), 322-322 | es |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.uri | http://hdl.handle.net/10201/113628 | - |
dc.description | ©<2017>. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Green Chemistry]. To access the final edited and published work see[DOI: 10.1039/x0xx00000x] | - |
dc.description.abstract | The biocatalytic synthesis of monoacylglycerides (MAGs) was carried out by the direct esterification of fatty acids (i.e. oleic, palmitic, myristic and lauric acids, respectively) with glycerol in different ionic liquids (ILs) based on cations with long alkyl side-chains (i.e. 1-hexadecyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C16mim][NTf2], 1-dodecyl-3-methylimidazolium tetrafluoroborate [C12mim][BF4]). Although all ILs have been shown as suitable reaction media for Novozym 435-catalyzed esterification of glycerol with free fatty acid, a highly selective selectivity of MAGs was only observed for the [C12mim][BF4] case (i.e up to 99% selectivity and yield for the monolaurin case). Furthermore, as these ILs are temperature switchable ionic liquid/solid phases that behave as sponge-like system, a straightforward protocol for IL-free MSGs recovery, based on iterative centrifugations at controlled temperature, has been developed. | es |
dc.format | application/msword | es |
dc.format.extent | 7 | es |
dc.language | eng | es |
dc.publisher | RSC | es |
dc.relation | Nombre del proyecto: Procesos quimio-enzimáticos sostenibles de interés industrial en líquidos iónicos tipo esponja y fluidos supercríticos. Código: CTQ-2015-67927-R. Agencia/entidad financiadora: Ministerio de Ciencia e Innovación (MINECO/FEDER). Ámbito Nacional. Retos Investigación: Proyectos I+D+i 2017. Convocatoria 2018. Nombre del proyecto: Procesos quimio-enzimáticos basados en la química verde: Aplicaciones a la obtención de biocombustibles de 2ª generación y la valorización del glicerol. Código: 19278/PI/14. Agencia/entidad financiadora: Fundación Séneca. Ámbito Nacional Ámbito Nacional, Ayudas a la realización de proyectos para el desarrollo de investigación científica y técnica por Grupos Competitivos. Convocatoria 2014. | es |
dc.rights | info:eu-repo/semantics/openAccess | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Enzymatic Glycerolysis | es |
dc.subject | Nonconventional Media | es |
dc.subject | Chemical-Processes | es |
dc.subject | Carbon-Dioxide | es |
dc.subject | Lipase-B | es |
dc.subject | Catalysis | es |
dc.subject | Esterification | es |
dc.subject | Stabilization | es |
dc.subject | Transition | es |
dc.subject | Stability | es |
dc.subject.other | CDU::5 - Ciencias puras y naturales::54 - Química | es |
dc.title | Highly selective biocatalytic synthesis of monoacylglycerides in sponge-like ionic liquids | es |
dc.type | info:eu-repo/semantics/article | es |
dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2017/gc/c6gc01969b | es |
dc.identifier.doi | 10.1039/C6GC01969B | - |
Aparece en las colecciones: | Artículos: Bioquímica y Biología Molecular "B" e Inmunología |
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Highly selective biocatalytic synthesis.pdf | 743,17 kB | Adobe PDF | ![]() Visualizar/Abrir |
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