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10.1021/acs.organomet.8b00920
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Pérez-Gómez, Marta | - |
dc.contributor.author | Azizollahi, Hamid | - |
dc.contributor.author | Franzoni, Ivan | - |
dc.contributor.author | Larin, Egor M. | - |
dc.contributor.author | Lautens, Mark | - |
dc.contributor.author | García-López, José-Antonio | - |
dc.contributor.other | Departamento de Química Inorgánica | es |
dc.date.accessioned | 2021-01-28T12:16:08Z | - |
dc.date.available | 2021-01-28T12:16:08Z | - |
dc.date.created | 2019 | - |
dc.date.issued | 2019-02-06 | - |
dc.identifier.citation | Organometallics, 2019, 38, 973-980 | es |
dc.identifier.issn | 1520-6041 | - |
dc.identifier.uri | http://hdl.handle.net/10201/101965 | - |
dc.description.abstract | We report here a proof of concept for the cleavage of unstrained remote Csp3–Csp3 bonds at room temperature assisted by a directing group, opening up new possibilities to use aliphatic carboxylic acids as suitable alkenyl coupling partners. This strategy involves the Pd-mediated Csp3–H activation directed by a tethered 8-aminoquinoline group, followed by a concerted asynchronous carbene insertion into the Pd–C bond, and an unexpected β-carbon-carbon bond splitting. The insertion of a coupling partner into a Pd–C bond is a novel route to promote C–C bond cleavage, which, in contrast to most common methodologies, does not rely on the use of strained carbocycles. | es |
dc.format | application/pdf | es |
dc.language | eng | es |
dc.relation | Ámbito del proyecto: nacional Agencia/entidad financiadora: MINECO Convocatoria: 2015 Nombre del proyecto: Synthesis and Applications in Catalysis and Photocatalysis of New Types of Transition Metal Organometallic Complexes (CTQ2015-69568-P) Código: CTQ2015-69568-P Ámbito del proyecto: regional Agencia/entidad financiadora: FUNDACIÓN SÉNECA Convocatoria: 2015 Synthesis, Structure and Reactivity of New Types of Organometallic Complexes. Applications as Synthetic Intermediates, Catalysts and Photoactive Materials. (19890/GERM/15) Código: 19890/GERM/15 | es |
dc.relation.isreplacedby | https://doi.org/10.1021/acs.organomet.8b00920 | es |
dc.rights | info:eu-repo/semantics/openAccess | es |
dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
dc.subject | Palladium | es |
dc.subject | C–H activation | es |
dc.subject | diazocompounds | es |
dc.subject | C–C cleavage | es |
dc.subject.other | CDU::5 - Ciencias puras y naturales::54 - Química | es |
dc.title | Tandem Remote Csp3−H Activation/Csp3−Csp3 Cleavage in Unstrained Aliphatic Chains Assisted by Palladium(II) | es |
dc.type | info:eu-repo/semantics/article | es |
dc.relation.publisherversion | https://doi.org/10.1021/acs.organomet.8b00920 | es |
dc.identifier.doi | 10.1021/acs.organomet.8b00920 | - |
Aparece en las colecciones: | Artículos: Química Inorgánica |
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Manuscript-revised-OM-2019-973.pdf | 76,49 MB | Adobe PDF | Visualizar/Abrir |
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