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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Portugués, Alejandro | - |
dc.contributor.author | López-García, Inmaculada | - |
dc.contributor.author | Jiménez-Bernad, Javier | - |
dc.contributor.author | Bautista, Delia | - |
dc.contributor.author | Gil-Rubio, Juan | - |
dc.contributor.other | Facultad de Química. Departamento de química Inorgánica | es |
dc.date.accessioned | 2021-01-28T11:31:35Z | - |
dc.date.available | 2021-01-28T11:31:35Z | - |
dc.date.issued | 2019-09-04 | - |
dc.identifier.citation | Chemistry–A European Journal 2019, vol. 25, pags. 15535 – 15547 | es |
dc.identifier.issn | 1521-3765 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/10201/101948 | - |
dc.description.abstract | The study of perfluoroalkyl metal complexes is key to understanding and improving metal-promoted perfluoroalkylation reactions. Herein we report the synthesis of the first gold complexes with primary or secondary perfluoroalkyl ligands by photoinitiated reactions between Au(I) organometallic complexes and iodoperfluoroalkanes. Complexes of the types LAuRF (L = PPh3 or N,N-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; RF = n-C4F9, n-C6F13, i-C3F7, c-C6F11) and [Au(RF)(Ar)I(PPh3)] (Ar = 2,4,6-trimethylphenyl) have been isolated and characterized. Alkynes RFC≡CR were formed by reaction of Ph3PAuC≡CR (R = Ph, nHex) with IRF (RF = n-C4F9, i-C3F7). Evidences of a photoinitiated radical mechanism for these reactions have been obtained. Au(III) complexes [Au(n-C4F9)(X)(Y)L] (X = Y = Cl, Br, I, Me; X = Me, Y = I) have been prepared or in situ generated, and their thermal or photochemical decomposition reactions have been studied | es |
dc.format | application/pdf | es |
dc.format.extent | 14 | es |
dc.language | eng | es |
dc.publisher | Wiley | es |
dc.relation | Proyecto 1 Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: Ministerio de Ciencia, Innovación y Universidades, FEDER Convocatoria: 2015 Nombre del proyecto: Síntesis y aplicaciones en catálisis y fotocatálisis de nuevos tipos de complejos organometálicos de metales de transición Código: CTQ2015-69568-P Proyecto 2 Ámbito del proyecto (Europeo, nacional o regional): Regional Agencia/entidad financiadora: Fundación Séneca de la Región de Murcia Convocatoria: 2014 Nombre del proyecto: SYNTHESIS, STRUCTURE AND REACTIVITY OF NEW TYPES OF ORGANOMETALLIC COMPLEXES. APPLICATIONS AS SYNTHETIC INTERMEDIATES, CATALYSTS AND PHOTOACTIVE MATERIALS Código: 19890/GERM/15 | es |
dc.relation.isreplacedby | https ://doi.org/10.1002/chem.201903058 | es |
dc.rights | info:eu-repo/semantics/openAccess | es |
dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
dc.subject | fluorinated ligands | es |
dc.subject | Gold | es |
dc.subject | oxidative addition | es |
dc.subject | photochemical reactions | es |
dc.subject | radicals | es |
dc.subject.other | CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica | es |
dc.title | Haloperfluorocarbons with Gold(I) Organometallic Complexes. Perfluoroalkyl Gold(I) and Gold(III) Complexes | es |
dc.type | info:eu-repo/semantics/article | es |
dc.relation.publisherversion | https ://doi.org/10.1002/chem.201903058 | es |
dc.identifier.doi | 10.1002/chem.201903058 | - |
Aparece en las colecciones: | Artículos: Química Inorgánica |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
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CEJ 2019.pdf | Chem. Eur. J. 2019, 25, 15535 – 15547 | 3,51 MB | Adobe PDF | Visualizar/Abrir |
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